4.7 Article

Molecular rotors in hierarchically ordered mesoporous organosilica frameworks

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 39, Pages 4798-4800

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b809559k

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Funding

  1. FIRB
  2. MIUR (Italy)
  3. U. S. Department of Energy, Basic Energy Sciences, Catalysis Science [DE-FG02-03ER15467]
  4. National Science Foundation [DMR05-20415]

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Diphenylene moieties, molecularly ordered in the framework of periodic mesoporous organosilicas, behave as molecular rotors and show a mobility with correlation times as short as a few nanoseconds.

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