Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 41, Pages 5098-5100Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b813369g
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Funding
- Korean Research Foundation [KRF-2006-312-C00587]
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The Blaise reaction intermediate, a zinc bromide complex of beta-enamino ester, could be activated in situ by addition of a stoichiometric or catalytic amount of n-BuLi to allow chemoselective tandem C2-acylation providing alpha-acyl-beta-enamino esters, which are valuable intermediates for the syntheses of tri- and tetrasubstituted pyrazoles.
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