4.7 Article

Palladium-catalyzed three-component coupling of arynes with allylic acetates or halides and terminal alkynes promoted by cuprous iodide

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 18, Pages 2158-2160

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b800118a

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Benzynes react with allylic acetates or halides and terminal alkynes in the presence of Pd(PPh3)(4), CuI and CsF in CH3CN at 50 degrees C for 5 h to give 1-allyl-2-alkynylbenzene derivatives in good to excellent yields.

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