4.7 Article

Facile intramolecular C(sp(3))-H bond activation with Pd(II)

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 24, Pages 2777-2778

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b802185f

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The treatment of bis(4-tert-butylthiazolyl) isoindoline (4-tBu-BTI) with palladium acetate results in the exclusive formation of an organometallic Pd(II) compound with C-H activated t-butyl group and a hemilabile S-coordinated thiazole donor in cis-position.

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