Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 22, Pages 2265-2266Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b006136k
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Co-II(porphyrin) complexes catalyse the reaction of aromatic azides, ArN3, with hydrocarbons containing a benzylic group, (RRRCH)-R-1-R-2-C-3, to give the corresponding amines, (RRRC)-R-1-R-2-C-3-NHAr. When at least one of the R-1-R-3 substituents is hydrogen, the catalytic reaction proceeds further to give the imines (RRC)-R-1-C-2=NAr in good yields.
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