4.7 Article

Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 23, Pages 2638-2640

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b805606d

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Funding

  1. Engineering and Physical Sciences Research Council [EP/D076889/1, EP/E036244/1] Funding Source: researchfish
  2. EPSRC [EP/D076889/1, EP/E036244/1] Funding Source: UKRI

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The new synergic base [PMDET center dot AK(TMP)(Et) Zn(Et)] selectively zincates 4-(dimethylamino) pyridine at the 2-position and 4- methoxypyridine at the 3-position, to afford bimetallic potassium pyridylzinc complexes each displaying a novel, but remarkably different, structure.

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