Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 47, Pages 6354-6356Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b815845b
Keywords
-
Categories
Funding
- Japan Society of the Promotion of Science (JSPS)
Ask authors/readers for more resources
A mild and efficient process for the direct-type catalytic allylation of sulfonylimidates has been developed; this reaction represents the first example of Bronsted base-catalysed, in situ generation and use of alpha-alkyl enolates in substitution reactions; the success of this methodology stems from the tunable alpha-proton acidity and nucleophilicity of sulfonylimidates, which could be harnessed in the realization of a broader range of catalytic direct-type reactions using ester equivalents as nucleophiles.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available