Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 15, Pages 1744-1746Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b717571j
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A new compartmental pyrazole-derived chelating ligand, four equivalents of mesitylcopper and stoichiometric amounts of di-oxygen lead to the formation of a remarkably stable organometallic framework that can be described as a heteroleptic O-centered cuprate anion [(MesCu(I))(4)(mu(4)-O)](2-) linked via sigma-mesityl-bridges to two surrounding binuclear Cu(I)-pyrazolate clamps.
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