Solvatomagnetic effect and spin-glass behavior in a 1D coordination polymer constructed from EE-azido bridged (Mn3O)-O-III units

The non-uniform chain manganese(III) complex constructed from EE-azido bridged Mn-III O-3 units, [Mn-III O-3(Brppz) (3)- MeOH)(3)(N-3)]center dot 2MeOH [1, Brppz = 3-(5-bromo-2-phenolate)-pyrazolate], is the first example of 1D azido-bridged coordination polymer showing both solvatomagnetic effect and spin-glass behavior.