4.7 Article

Heavier group 2 element-catalysed hydroamination of isocyanates

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 41, Pages 5206-5208

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b809649j

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Funding

  1. GlaxoSmithKline
  2. Royal Society for a University Research Fellowship
  3. Royal Society Wolfson Research Merit Award
  4. Engineering and Physical Sciences Research Council
  5. Engineering and Physical Sciences Research Council [EP/E03117X/1] Funding Source: researchfish
  6. EPSRC [EP/E03117X/1] Funding Source: UKRI

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The heteroleptic calcium amides [{ArNC(Me)CHC(Me)NAr}Ca(NR(2))(THF)] (Ar = 2,6-di-iso-propylphenyl, R = SiMe(3), Ph) and the homoleptic heavier alkaline earth amides, [M{N(SiMe(3))(2)}(2)] (M = Ca, Sr and Ba) are reported as pre-catalysts for the hydroamination of isocyanates.

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