4.7 Article

An organopalladium chromogenic chemodosimeter for the selective naked-eye detection of Hg2+ and MeHg+ in water-ethanol 1 : 1 mixture

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 38, Pages 4576-4578

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b807670g

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Funding

  1. DGI of Spain [CTQ2006-15456-C04-04BQU]
  2. Junta de Castilla y Leon
  3. Consejeria de Educacion y Cultura
  4. Fondo Social Europeo [BU013A06]
  5. European Commission [LIFE05 ENV/E/000333-Hydrosolar 21]
  6. SCAI-UBU

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An organopalladium chemical dosimeter of Hg2+ that methylates Hg2+, undergoing a colour change in 1 : 1 ethanol-water with submicromolar sensitivity, gives rise to an aqua-palladium complex that is methylated by MeHg+ in the presence of a dithiol compound, undergoing another colour change, thus making the system suitable for the naked-eye detection of Hg2+ and MeHg+, two environmentally important species of Hg2+.

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