4.7 Article

Enantioselective rhodium-catalysed 1,4-additions of 2-heteroarylzinc donors using Me-DUPHOS

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 32, Pages 3795-3797

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b806098c

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Funding

  1. EPSRC
  2. University of Bath
  3. Engineering and Physical Sciences Research Council [EP/D075351/1] Funding Source: researchfish
  4. EPSRC [EP/D075351/1] Funding Source: UKRI

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The enantioselective 1,4-addition of 2-(substituted)thienylzinc and 2-furanylzinc reagents has been achieved (up to 99 : I er) using a complex derived from [Rh(C2H4)(2)CI](2) and Me-DUPHOS.

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