4.7 Article

Highly chemo- and regio-selective [2+2+2] cycloaddition of unsymmetrical 1,6-diynes with terminal alkynes catalyzed by Cp*Ru(cod)Cl under mild conditions

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 7, Pages 549-550

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b000466i

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Ru(II)-catalyzed cycloaddition of unsymmetrical 1,6-diynes gives the desired cycloadducts in high yields with a regioselectivity meta : ortho = 88 : 12-98 : 2.

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