Structural instability associated with the tilting of CuO6 octahedra in La2-xSrxCuO4

Comprehensive inelastic neutron-scattering measurements were performed to study the soft optical phonons in La2-xSrxCuO4 at x = 0.10, 0.12 and 0.18. We found at x = 0.18 that the softening of Z-point phonon, suggesting incipient structural transition from the low-temperature orthorhombic (LTO) to low-temperature tetragonal (LTT) phase, breaks at T-c, which is consistent with the previous report by Lee et al. for the optimally doped x = 0.15 sample. As for x = 0.10 and 0.12, on the other hand, the softening continues even below T-c. It is thus clarified that the breaking of soft phonon is characteristic of La2-xSrxCuO4 in the optimally and overdoped regions. In the course of studying the soft phonons, we discovered that a central peak remains above the LTO to high-temperature tetragonal (HTT) phase transition at T-s1 and splits into incommensurate components along title [1 1 0](HTT) direction at higher temperatures. This is a common feature for both x = 0.12 and 0.18 and their temperature dependences of the splitting 2 delta can be scaled by using a renormalized temperature T/T-s1. In the high temperature limit, delta saturates around delta similar to 0.12 r.l.u., which value is close to the splitting of incommensurate magnetic signals. This implies that the incipient lattice modulation starts appearing at very high temperature. Details of this modulation and its relations with other properties are, however, not yet clarified.