Journal
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Volume -, Issue 3, Pages 353-359Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/a907545c
Keywords
-
Categories
Ask authors/readers for more resources
Using sterically hindered 2,9-diarylphenanthrolines (I) as well as unsubstituted or 4,7-disubstituted phenanthrolines (II) the first preparation of open chain heteroleptic bis(phenanthroline) complexes [M(I)(II)](n+) with M=Ag+ or Zn2+ has been realised. Their structure was confirmed by electrospray MS, NMR and in one case X-ray data. With two sets of phenanthroline ligands, three stereoisomers of [M(I)(II)](+) were detected in the silver(I) and for comparative reasons in the corresponding copper(I) complexes. On the basis of NMR experiments these were assigned as in-in, in-out and out-out isomers.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available