Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 152, Issue 1-2, Pages 111-115Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S1381-1169(99)00269-1
Keywords
metalloporphyrins; cyclic olefins; epoxidation
Categories
Ask authors/readers for more resources
Metalloporphyrins with several nitro groups in beta-positions were used in the epoxidation of cyclic olefins with magnesium monoperoxyphthalate (MMPP) as an oxygen atom donor, under mild conditions. Iron- and manganese-pernitrated complexes are; able to promote the epoxidation of alkenes without requiring the addition of any nitrogen base. Cobalt porphyrins showed low activity, but addition of the cocatalyst raised it. (C) 2000 Elsevier Science B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available