Journal
SOLID STATE IONICS
Volume 127, Issue 1-2, Pages 151-156Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0167-2738(99)00262-3
Keywords
BIMEVOX; vanadium compounds; Raman scattering; crystal structure
Categories
Ask authors/readers for more resources
The Raman spectra of BIMEVOX (ME = Mg, Ni, Cu, Zn) single crystals are reported. The main features of the spectra observed in the 600 to 900 cm(-1) frequency range are assigned to the stretching vibrations of the V-O bonds. Interpretation of the Raman spectra is based on the diatomic approximation and the correlation between the frequencies of stretching vibrations of vanadium-oxygen bonds and bond lengths. V-O bond orders are determined from an empirical relation between these frequencies and bond orders. The results point to predominantly tetrahedral coordination of vanadium in the studied BIMEVOX systems. (C) 2000 Elsevier Science B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available