Journal
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Volume -, Issue 15, Pages 2491-2494Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b001310m
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Stereochemical evidence suggests that acid catalysed citran formation proceeds via electrocyclisation of a dienone, and that pyrolysis of 'farnesylidenemalonic acid' proceeds with retention of configuration at the newly formed 8-olefin bond, indicating the operation of forward and reverse Diels-Alder processes respectively; 1,3-dihydroxynaphthalene reacts with citral in pyridine to yield chromene and citran products in a regioselective fashion.
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