Structural analysis of calcium spirulan (Ca-SP)-derived oligosaccharides using electrospray ionization mass spectrometry

Detailed structural analyses of calcium spirulan (Ca-SP)-derived oligosaccharides were performed by ESI-MS and collision-induced dissociation tandem mass spectrometry. This study indicates that Ca-SP is composed of two types of disaccharide repeating units, O-rhamnosyl-acofriose and O-hexuronosyl-rhamnose (aldobiuronic acid).