Journal
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 60, Issue 2, Pages 641-658Publisher
KLUWER ACADEMIC PUBL
DOI: 10.1023/A:1010167626551
Keywords
Ca(OH)(2); multiple-step kinetics; multivariate non-linear regression
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In principle, the kinetic analysis of thermal effects has limitations when based on a single measurement. Using a simulated example and the dehydration of Ca(OH)(2), it will be shown that, through the simultaneous application of non-linear regression to several measurements run at different heating rates (multivariate non-linear regression), the difficult problem of determining the probable reaction type can be reliably solved.
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