Journal
MATERIALS TRANSACTIONS JIM
Volume 41, Issue 9, Pages 1111-1113Publisher
JAPAN INST METALS
DOI: 10.2320/matertrans1989.41.1111
Keywords
delafossite; copper indium oxide; ion exchange reaction; holding time; structure refinement
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New delafossite-type CuInO2 was synthesized by ion exchange reaction of CuCl with alpha -NaFeO2-type NaInO2 or with alpha- LiFeO2-type LiInO2. According to die XRD, after 144h the main product obtained at 623 K was CuInO2 in either starting material. Lattice parameters of CuInO2 derived from NaInO2 or LiInO2 as determined by Rietveld analysis, are a = 329.01pm, c = 1738.8 pm, and a = 329.22 pm, c = 1738.8 pm, respectively.
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