4.4 Article

Hamiltonian derivation of a detailed fluctuation theorem

Journal

JOURNAL OF STATISTICAL PHYSICS
Volume 98, Issue 1-2, Pages 77-102

Publisher

SPRINGER
DOI: 10.1023/A:1018670721277

Keywords

fluctuation theorem; irreversible processes

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We analyze the microscopic evolution of a system undergoing a far-from-equilibrium thermodynamic process. Explicitly accounting for the degrees of freedom of participating heat reservoirs. we derive a hybrid result: similar in form to both the fluctuation theorem and a statement of detailed balance. We relate this result to the steady-state fluctuation theorem and to a ii-re energy relation valid far from equilibrium.

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