Journal
JOURNAL OF CARBOHYDRATE CHEMISTRY
Volume 20, Issue 9, Pages 833-839Publisher
MARCEL DEKKER INC
DOI: 10.1081/CAR-100108660
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The biocatalytic transformation of acrolein into (S)-2-hydroxybut-3-enenitrile using the (S)-hydroxynitrile lyase from Hevea brasiliensis followed by Grignard C-elongation, asymmetric epoxidation and nucleophilic ring-opening afforded 1-deoxy-D-xylulose (1) in 47% overall yield.
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