Journal
CHEMCATCHEM
Volume 6, Issue 3, Pages 763-766Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201301062
Keywords
alkenes; alkylboronates; hydroboration; iron; pinacolborane
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Funding
- CNRS
- University of Rennes 1
- Ministre de l'Enseignement Suprieur et de la Recherche
- ANR program [ANR-12-BS07-0011]
- Axa Research Funds
- Agence Nationale de la Recherche (ANR) [ANR-12-BS07-0011] Funding Source: Agence Nationale de la Recherche (ANR)
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[(IMes)Fe(CO)(4)] [IMes=1,3-bis(2,4,6-trimethylphenyl) imidazol-2-ylidene] complex was found to be an efficient pre-catalyst for the hydroboration of functional alkenes in the presence of pinacolborane at room temperature. Notably, UV irradiation (350nm) is important to promote this catalytic transformation. Interestingly, high chemo- and regioselectivities were observed as only anti-Markovnikov boronate derivatives were obtained and various functional groups can be tolerated.
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