4.6 Article

Catalytic Hydrogen Evolution by Tungsten Disulfide at Liquid-Liquid Interfaces

Journal

CHEMCATCHEM
Volume 6, Issue 10, Pages 2832-2835

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201402473

Keywords

electrochemistry; electron transfer; hydrogen; interfaces; tungsten

Funding

  1. TUBITAK (The Scientific and Technological Research Council of Turkey) [211T185]
  2. COST Action [MP1106]
  3. TUBA (Turkish Academy of Sciences)
  4. TUBITAK [2210-C]
  5. Selcuk University Scientific Research Projects (BAP)

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WS2, which is composed of cheap and earth-abundant elements, catalyzes the hydrogen-evolution reaction efficiently using the organic electron-donor decamethylferrocene. This catalytic activity has been investigated at liquid-liquid interfaces (water-1,2-dichloroethane) by voltammetry and biphasic reactions observed by UV/Vis spectroscopy and GC.

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