Journal
CHEMCATCHEM
Volume 6, Issue 8, Pages 2229-2234Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201402299
Keywords
biomass; hydroxymethylfurfural; homogeneous catalysis; polar aprotic solvent; tetrahydrofuran
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Funding
- Institute for Atom-efficient Chemical Transformations (IACT), an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences
- National Science Foundation [CHE-1004690]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1004690] Funding Source: National Science Foundation
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Herein, we report a new reaction pathway to produce hydroxymethylfurfural (HMF) from cellulose under mild reaction conditions (140-190 degrees C; 5 mm H2SO4) in polar aprotic solvents (i.e. THF) without the presence of water. In this system, levoglucosan is the major decomposition product of cellulose, followed by dehydration to produce HMF. Glucose, levulinic acid, and formic acid are also produced as a result of side reactions with water, which is a by-product of dehydration. The turnover frequency for cellulose conversion increases as the water content in the solvent decreases, with conversion rates in THF being more than twenty times higher than those in water. The highest HMF yield from cellulose was 44% and the highest combined yield of HMF and levulinic from cellulose was 53%, which are nearly comparable to yields obtained in ionic liquids or biphasic systems. Moreover, the use of a low boiling point solvent, such as THF, facilitates recovery of HMF in downstream processes.
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