Journal
CHEMCATCHEM
Volume 6, Issue 8, Pages 2175-2187Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201402288
Keywords
C-H activation; heterogeneous catalysis; palladium; supported catalysts; sustainable chemistry
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Funding
- University of Nantes
- Centre National de la Recherche Scientifique (CNRS)
- Region Pays de la Loire in the framework of a recrutement sur poste strategique
- Agence Nationale de la Recherche [ANR JCJC 7141]
- CNRS
- University of Lyon
- Region Rhone-Alpes [07 016376 01/02/03]
- French National Agency of Research [ANR-07-BLAN-0167-01/02, ANR-12-CDII-0001_01]
- Agence Nationale de la Recherche (ANR) [ANR-07-BLAN-0167] Funding Source: Agence Nationale de la Recherche (ANR)
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This review gives an overview of direct C-H arylation catalyzed by heterogeneous Pd catalysts. The efficiency of the different forms of heterogeneous Pd catalysts is discussed with a critical view of the transformations attainable. If experimental evidence is provided, mechanistic considerations on the true nature of the catalysis, that is, heterogeneous versus homogeneous, are discussed as well.
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