Journal
CHEMCATCHEM
Volume 6, Issue 1, Pages 67-75Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201300493
Keywords
artificial enzyme; biomimetic synthesis; heterogeneous catalysis; mesoporous materials; metal-organic frameworks; microporous materials
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Funding
- Center for Gas Separations Relevant to Clean Energy Technologies, an Energy Frontier Research Center
- U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences [DE-SC0001015]
- DOE EERE Hydrogen Program [DE-FC36-07GO17033]
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In this Minireview, we have summarized the recent progress of biomimetic catalysis in the field of metal-organic frameworks (MOFs) with a focus on the implantation of biomimetic active sites into a stable MOF. In addition, the potential of creating highly selective catalytic pockets and diffusion-favored hierarchical structures in MOFs has also been explored. Furthermore, we have highlighted the achievements of MOF catalysts in the applications as mimics of peroxidase, cytochromes P450, hemoglobin, and photosynthetic systems.
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