4.6 Article

Sonication-Assisted Low-Temperature Routes for the Synthesis of Supported Fe-TiO2 Econanomaterials: Partial Photooxidation of Glucose and Phenol Aqueous Degradation

Journal

CHEMCATCHEM
Volume 5, Issue 8, Pages 2270-2277

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201300025

Keywords

heterogeneous catalysis; nanostructures; phenol photomineralization; selective photocatalysis; ultrasonic

Funding

  1. Marie Curie International Reintegration Grant within the 7th European Community Framework Programme
  2. Ministry of Science and Higher Education of Poland [473/7.PR/2012]

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Fe-doped (2)-supported photocatalytic materials prepared by the use of a mild ultrasound-assisted protocol have been found to possess excellent selectivities in glucose oxidation and total phenol mineralization. (2) physisorption, X-ray photoelectron spectroscopy, SEM with X-ray microanalysis, HR (3+) ions. (2) supported on zeolite. In phenol photodegradation, although Fe doping demonstrated the detrimental effect on the conversion rate, an improvement in the direct mineralization of phenol to CO2 and water, particularly for the SiO2-supported photocatalyst, with a negligible content of toxic byproducts in water has been observed in comparison with commercially available Evonik P25.

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