Journal
CHEMCATCHEM
Volume 6, Issue 2, Pages 473-478Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201300749
Keywords
alcohols; copper; iron; structure-activity relationships; synthesis design
Categories
Funding
- US Department of Energy [DE-FG3606GO86025, DE-FC2608NT01923]
- US Department of Agriculture [2012-10008-20302]
- Direct For Biological Sciences
- Div Of Biological Infrastructure [1126743] Funding Source: National Science Foundation
Ask authors/readers for more resources
We show that higher alcohols can be produced with high selectivity from syngas over three-dimensionally ordered macroporous Cu-Fe catalyst. The catalyst was developed by using a glyoxylate route colloidal crystal template method. The high intrinsic activity was ascribed to three factors. First, the unique ordered structure has a large pore size and interconnected macroporous tunnels of the catalyst with a large accessible surface area improves the catalytic activity. Second, a high density of uniformly distributed defective Cu-0 and chi-Fe5C2 nanoparticles derived from the glyoxylate route helps to provide abundant, active, stable dual sites. Third, atomic steps on the Cu surface, induced by planar defects and lattice strain, serve as high-activity oxygenation sites; and active chi-Fe5C2 chain-growth sites surrounds the defective and strained form of Cu surface intimately, which results in a synergetic effect between the active and stable Cu-FexCy dual sites for higher alcohols synthesis.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available