4.6 Article

Ag/AgBr-Grafted Graphite-like Carbon Nitride with Enhanced Plasmonic Photocatalytic Activity under Visible Light

Journal

CHEMCATCHEM
Volume 5, Issue 8, Pages 2343-2351

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201300144

Keywords

silver; heterogeneous catalysis; environmental chemistry; photochemistry; reaction mechanisms

Funding

  1. National Natural Science Foundation of China [21273080, 21043005]
  2. Guangdong Natural Science Foundation [S2012010008383]

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Ag/AgBr-grafted graphite-like carbon nitride (g-C3N4) is fabricated by the insitu photoreduction of AgBr/g-C3N4 hybrids prepared by a deposition-precipitation method. N-3(4) hybrids exhibit a strong absorbance in the visible and near-IR region because of the surface plasmon resonance absorption of Ag nanocrystals. Compared with bare g-C3N4 and Ag/AgBr nanoparticles, a 28-fold and six-fold enhancement in the degradation rate of rhodamine B is observed over Ag/AgBr/g-C3N4 hybrids under visible-light irradiation, respectively. N-3(4) system. Moreover, the composite can be reclaimed easily by sedimentation without any decrease of its photocatalytic activity. N-3(4)-based plasmonic photocatalysts and facilitates their practical application to solve environmental issues.

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