Journal
CHEMCATCHEM
Volume 5, Issue 8, Pages 2360-2366Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201300035
Keywords
boron; chemoselectivity; hydrogenation; heterogeneous catalysis; palladium
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Funding
- Grants-in-Aid for Scientific Research [12J10137] Funding Source: KAKEN
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The hydrogenation catalyzed heterogeneously by palladium on boron nitride (Pd/BN) in methanol realized the chemoselective hydrogenation of only azides, alkenes, and alkynes in the presence of other reducible functionalities such as benzyl ethers, aryl halides, aryl ketones, and nitro groups. Further-more, the totally chemoselective semihydrogenation of alkynes could also be achieved without the reduction of other coexisting reducible functionalities, which include azides and alkenes, by using Pd/BN in pyridine as a solvent.
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