Journal
CHEMCATCHEM
Volume 5, Issue 4, Pages 986-993Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201200562
Keywords
heterogeneous catalysis; interparticle mesoporosity; ironsilica; nanoparticles; oxidation
Categories
Funding
- Bulgarian Scientific Fund (Bulgaria-Slovenia bilateral project) [HTC 02/205]
- Slovenian Research Agency [P1-0021, Z1-9144, BI-HU/11-12-010, BI-BG/11-12-009]
- EN-FIST Centre of Excellence
Ask authors/readers for more resources
Catalytic oxidation is one of the most important industrially applicable processes for the decomposition of volatile organic compounds (VOCs) in polluted air. The advanced VOC removal process is composed of an adsorption unit and a catalytic incinerator. Many efforts have been made to design a combined adsorptioncatalytic unit with optimal activity and selectivity. We demonstrate that iron-functionalized silica nanoparticles with interparticle mesoporosity (FeKIL-2) act as highly efficient adsorbents and catalysts with optimal Fe/Si molar ratios of 0.01 in toluene oxidation as model VOCs in the gas phase. By using UV/Vis, FTIR, and Mossbauer spectroscopic techniques, we prove that the enhanced activity of the catalyst is attributed to iron incorporated into the silica matrix, which depends on the iron content. The iron content with Fe/Si0.01 leads to the formation of stable Fe3+ ions in the silica matrix, which ensures easier oxygen release from the catalyst (Fe3+/Fe2+ redox cycles). The increase in the iron content with Fe/Si>0.01 leads to the formation of oligonuclear iron complexes. The material thus introduces a promising, environmentally friendly, cost-effective, and highly efficient catalyst with combined adsorption and catalytic properties for the removal of low-concentration VOC from polluted air.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available