Journal
CHEMCATCHEM
Volume 5, Issue 12, Pages 3548-3551Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201300886
Keywords
catalysis; hydride; isomerization; olefin metathesis; ruthenium
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
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Two ruthenium hydride complexes commonly proposed as agents of unintended isomerization during olefin metathesis are examined for their activity in isomerization of estragole, a representative allylbenzene. Neither proves kinetically competent to account for the levels of isomerization observed during cross-metathesis of estragole by the second-generation Grubbs catalyst. A structure-activity analysis of selected ruthenium hydride complexes indicates that higher isomerization activity correlates with a more electrophilic metal center.
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