Journal
CHEMCATCHEM
Volume 4, Issue 4, Pages 432-445Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201100422
Keywords
cross-coupling; heterogeneous catalysis; immobilization; palladium; parallel synthesis
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A large number of immobilized-Pd-catalysts for cross-coupling reactions have been introduced in the last decade. Are the observed catalyzed reactions truly heterogeneous or are they homogeneous due to leached palladium? This account critically addresses the leaching issue by selectively referring to some of the newly developed catalytic systems in an attempt to evaluate said systems based on uniform criteria. The report is concluded by identifying the relevant chemical and structural challenges in the field.
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