Journal
CHEMCATCHEM
Volume 4, Issue 2, Pages 151-168Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201100266
Keywords
anhydrides; azlactones; desymmetrization; dynamic kinetic resolution; organocatalysis
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Funding
- Irish Research Council for Science Engineering and Technology (IRCSET)
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This review charts the recent progress of two related, yet distinct organocatalytic processes: the desymmetrisation of meso-anhydrides and the dynamic kinetic resolution of azlactones. Driven by recent advances in catalyst design, both these processes have undergone something of a renaissance in recent years and are now becoming very powerful and versatile synthetic methodologies. The material is presented in a critical fashion and the material is organised by reaction type and catalyst class.
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