Journal
CHEMCATCHEM
Volume 3, Issue 5, Pages 883-886Publisher
WILEY-BLACKWELL
DOI: 10.1002/cctc.201000458
Keywords
allylic ligands; asymmetric catalysis; palladium; phosphanes
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Funding
- French Ministry of Education and Research (MENESR)
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Chiral enantiopure 2-5-diphenylphospholane borane 8 is an interesting nucleophile for allylic phosphination in the presence of palladium complexes to form C-P bonds. A highly diaste-reoselective allylic phosphination reaction was realized using chiral palladium-DACH-naphthyl (DACH=1,2-diaminocyclohexane) ligand as the catalyst system. The secondary phosphineborane complex could be classified as a Nu(L) type nucleophile.
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