Journal
CHEMCATCHEM
Volume 1, Issue 4, Pages 510-514Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.200900118
Keywords
gold; metallic sols; nanoparticles; oxidation; stabilizing agents
Categories
Funding
- AIT-DADD
- Fondozione Cariplo
Ask authors/readers for more resources
Gold nanoparticles (Au NPS), stabilized by polyvinylalcohol (PVA), tetrakishydroxypropylphosphonium chloride (THPC), and citrate, have been synthesized and tested in the liquid-phase oxidation of glycerol. THPC-stabilized Au NPs have been found to exhibit remarkable catalytic activity (TOF=2478 h(-1)) in comparison to PVA- and citrate-stabilized nanoparticles (TOF=715 and 160 h(-1), respectively). The catalytic results can be explained in terms of particle size but aging treatment also revealed the influence of the protective agent. PVA as stabilizer produced small and quite stable gold nanoparticles differently from the THPC system. However PVA also limits the accessibility of reactant to the active site.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available