Journal
BIOELECTROCHEMISTRY
Volume 53, Issue 1, Pages 97-101Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0302-4598(00)00127-6
Keywords
self-assembled monolayer; cyclic voltammetry; XPS measurement; DL-homocysteine; myoglobin
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A pair of well-defined redox waves of myoglobin at a DL-homocysteine self-assembled gold electrode was achieved. Myoglobin can strongly bind to the homocysteine self-assembled gold electrode, so the Mb-Hcy self-assembled gold electrode was prepared and the standard rate constant (k(s)) of Mb was calculated as 9.3 x 10(-1) s(-1). X-ray photoelectron spectroscopy (XPS) measurements demonstrated that Hcy monolayer was formed and Mb was bound to Hcy monolayer. (C) 2000 Elsevier Science S.A. All rights reserved.
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