4.4 Article

The first synthetic route to furostan saponins

Journal

TETRAHEDRON LETTERS
Volume 42, Issue 1, Pages 77-79

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)01889-X

Keywords

furostan saponin; synthesis; glycosidation

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26-O-beta -D-Glucopyranosyl-22-methoxy-25(R)-furost-5-en-3 beta -ol 3-O-beta -D-glucopyranoside is synthesized from diosgenin in 11 steps and 26% overall yield. The present synthetic route represents the first one to furostan saponins. (C) 2000 Elsevier Science Ltd. All rights reserved.

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