Journal
TETRAHEDRON LETTERS
Volume 42, Issue 1, Pages 53-56Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)01877-3
Keywords
annulenes; cage compounds; complexation; copper and compounds; silver and compounds
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The copper(I) and silver(I) complexes of all-Z-tribenzo[12]annulene were synthesized and the structures were determined by X-ray analysis. The trigonal olefinic cavity of the [12]annulene incorporates copper and silver cations to produce stable complexes, whereas the gold(I) complex was unstable, yielding a cyclization product via isomerization of the Z-double bonds. (C) 2000 Elsevier Science Ltd. All rights reserved.
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