Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 1, Pages 107-108Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b006048h
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This work describes a new strategy for the preparation of hyperbranched polymers from commercially available A(2) and BB'(2) type monomers without any catalysts; the rapid reaction of A groups with B groups results in the formation of dimers that can be regarded as a new sort of AB'(2) type monomer; further polymerization of AB'(2) gives hyperbranched polymers; through this approach a new kind of water-soluble hyperbranched polysulfone-amine was synthesized by polyaddition of N-methylpropane-1,3-diamine (BB'(2)) to divinyl sulfone (A(2)).
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