4.7 Article

Intramolecular addition of acyl radicals to alpha-substituted vinylogous carbonates: demonstrating the effect of ring size on acyclic stereocontrol

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 23, Pages 2504-2505

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b106766b

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Funding

  1. NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM058877] Funding Source: NIH RePORTER
  2. NIGMS NIH HHS [GM58877] Funding Source: Medline

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The level of stereocontrol obtained in the reduction of the free radical derived from the intramolecular addition of an acyl radical to an alpha -branched vinylogous carbonate is dependent upon the ring-size of the cyclic ether.

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