4.7 Article

Synthesis of alpha-acetoxy and formyloxy ketones by thallium(III) promoted alpha-oxidation

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 11, Pages 956-957

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b102192n

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Treatment of ketones with thallium(iii) triflate in amide solvents at 60 degreesC for 30 min followed by addition of small amounts of H2O cleanly provided the corresponding alpha -acyloxy ketones.

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