Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 14, Pages 1262-1263Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b103986p
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The catalytic hydroxylation of alkanes by an electron-deficient cobalt( III) porphyrin complex and m-chloroperbenzoic acid yielded alcohols as major products with a high k(H)/k(D) value, > 99% retention of stereochemistry, and a high regioselectivity; a high-valent cobalt-oxo porphyrin complex was suggested as a reactive hydroxylating intermediate.
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