Journal
TETRAHEDRON
Volume 57, Issue 1, Pages 241-247Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)01005-X
Keywords
aromatic Friedel-Crafts alkylation; acylation; benzoylation; and sulfonylation reactions; copper(II)tri-fluoromethanesulfonate; tin(II)trifluoromethanesulfonate
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Aromatic electrophilic substitution reactions such as alkylation, acylation, benzoylation, and sulfonylation were studied in the presence of a catalytic amount of Cu(OTf)(2) and Sn(OTf)(2). Cu(OTf)(2) was very efficient for alkylation, acylation, and benzoylation reactions. However, in case of sulfonylation reactions, Sn(OTf)(2) gave better results. (C) 2000 Elsevier Science Ltd. Ail rights reserved.
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