Journal
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Volume -, Issue 20, Pages 3010-3014Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b101192h
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The combination of bpa with the pseudohalide cyanate (NCO-) leads to the preparation of two new isomorphous compounds exhibiting the formula [M(NCO)(2)(bpa)(2)](n). bpa where M = Co (1), Mn (2). Both of them have been magnetostructurally characterised by means of X-ray diffraction analysis, TG measurements, IR and ESR spectroscopies and measurements of the magnetic susceptibility. Both compounds consist of M-(gauche-bpa)(2)-M chains connected through H-bonds. The resulting network shows pseudo-channels (8.5 Angstrom x 9.3 Angstrom). The structure also exhibits anti-bpa groups performing as crystallisation molecules that are perpendicularly disposed to the pseudo-channels. Both compounds exhibit antiferromagnetic interactions through metallic centres.
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