3.8 Article

The first catena-trihydrogen triphosphide: synthesis and crystal structure of [Na(NH3)(5)][Na(NH3)(3)(P3H3)]

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b101533h

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The reaction of P-4 with sodium in liquid ammonia (P : Na ratio 3 : 5) yields crystalline NaNH2 and [Na(NH3)(5)][Na(NH3)(3)(P3H3)], which contains all-trans catena-P3H32- stabilised in the ion complex [Na(NH3)(3)(P3H3)](-).

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