Journal
SOLID STATE COMMUNICATIONS
Volume 120, Issue 4, Pages 161-164Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0038-1098(01)00367-2
Keywords
photoelectron spectroscopies; magnetically ordered materials
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The valences of Fe and Mo in Sr2FeMoO6 are investigated by means of X-ray absorption and photoemission spectroscopies. We find that the d occupations are similar to those of Fe in Fe2O3 and Mo in MoO3. Considering the covalency, however, we argue that the ground state is closer to a Fe+3(3d(5))-Mo+5(4d(1)) configuration than to a Fe+2(3d(6))-Mo+6(4d(0)) configuration. (C) 2001 Published by Elsevier Science Ltd.
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