Journal
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Volume -, Issue 3, Pages 219-221Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b009121i
Keywords
alkaline-earth metals; chemical vapour deposition; coordination chemistry; mass spectrometry; radicals
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In the synthesis of barium 3,5-dimethylpyrazolate, silicone joint grease and cyclo-(Me2SiO)(4) are cleaved and two O(SiMe2O)(2)(2-) bidentate chelating siloxane anions are coordinated above and below an unprecedented Ba-6(12-) layer framed by eight sigma/pi coordinated pyrazolate anions.
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